Ultra-Efficient and Cost-Effective Platinum Nanomembrane Electrocatalyst for Sustainable Hydrogen Production

Abstract

Abstract:

Hydrogen production through hydrogen evolution reaction (HER) offers a promising solution to combat climate change by replacing fossil fuels with clean energy sources. However, the widespread adoption of efficient electrocatalysts, such as platinum (Pt), has been hindered by their high cost. In this study, we developed an easy-to-implement method to create ultrathin Pt nanomembranes, which catalyze HER at a cost significantly lower than commercial Pt/C and comparable to non-noble metal electrocatalysts. These Pt nanomembranes consist of highly distorted Pt nanocrystals and exhibit a heterogeneous elastic strain field, a characteristic rarely seen in conventional crystals. This unique feature results in significantly higher electrocatalytic efficiency than various forms of Pt electrocatalysts, including Pt/C, Pt foils, and numerous Pt single-atom or single-cluster catalysts. Our research offers a promising approach to develop highly efficient and cost-effective low-dimensional electrocatalysts for sustainable hydrogen production, potentially addressing the challenges posed by the climate crisis.

Key words:Platinum,Hydrogen evolution reaction,Lattice distortion,Heterogeneous strain

Xiang Gao, Shicheng Dai, Yun Teng, Qing Wang, Zhibo Zhang, Ziyin Yang, Minhyuk Park, Hang Wang, Zhe Jia, Yunjiang Wang, Yong Yang. Ultra-Efficient and Cost-Effective Platinum Nanomembrane Electrocatalyst for Sustainable Hydrogen Production[J]. Nano-Micro Letters, 2024, 16(1): 108-.

Xiang Gao, Shicheng Dai, Yun Teng, Qing Wang, Zhibo Zhang, Ziyin Yang, Minhyuk Park, Hang Wang, Zhe Jia, Yunjiang Wang, Yong Yang. [J]. Nano-Micro Letters, 2024, 16(1): 108-.

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URL:https://www.qk.sjtu.edu.cn/nml/EN/10.1007/s40820-024-01324-5

https://www.qk.sjtu.edu.cn/nml/EN/Y2024/V16/I1/108

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References62

1.	J.A . Turner , Sustainable hydrogen production. Science 305, 972-974 ( 2004). https://doi.org/10.1126/science.1103197
2.	S . Chu , A . Majumdar , Opportunities and challenges for a sustainable energy future. Nature 488, 294-303 ( 2012). https://doi.org/10.1038/nature11475
3.	B . Huang , Z . Sun , G . Sun , Recent progress in cathodic reduction-enabled organic electrosynthesis: trends, challenges, and opportunities. eScience 2, 243-277 ( 2022). https://doi.org/10.1016/j.esci.2022.04.006
4.	M . Carmo , D.L . Fritz , J . Mergel , D . Stolten , A comprehensive review on PEM water electrolysis. Int. J. Hydrog. Energy 38, 4901-4934 ( 2013). https://doi.org/10.1016/j.ijhydene.2013.01.151
5.	L . An , C . Wei , M . Lu , H . Liu , Y . Chen et al., Recent development of oxygen evolution electrocatalysts in acidic environment. Adv. Mater. 33, e2006328 ( 2021). https://doi.org/10.1002/adma.202006328
6.	J . Mahmood , F . Li , S.-M . Jung , M.S . Okyay , I . Ahmad et al., An efficient and pH-universal ruthenium-based catalyst for the hydrogen evolution reaction. Nat. Nanotechnol. 12, 441-446 ( 2017). https://doi.org/10.1038/nnano.2016.304
7.	Z.W . Seh , J . Kibsgaard , C.F . Dickens , I . Chorkendorff , J.K . Nørskov et al., Combining theory and experiment in electrocatalysis: insights into materials design. Science 355, eaad4998 ( 2017). https://doi.org/10.1126/science.aad4998
8.	C . Li , N. Clament Sagaya Selvam , J . Fang , Shape-controlled synthesis of platinum-based nanocrystals and their electrocatalytic applications in fuel cells. Nano-Micro Lett. 15, 83 ( 2023). https://doi.org/10.1007/s40820-023-01060-2
9.	L . Ding , Z . Xie , S . Yu , W . Wang , A.Y . Terekhov et al., Electrochemically grown ultrathin platinum nanosheet electrodes with ultralow loadings for energy-saving and industrial-level hydrogen evolution. Nano-Micro Lett. 15, 144 ( 2023). https://doi.org/10.1007/s40820-023-01117-2
10.	J.N . Tiwari , S . Sultan , C.W . Myung , T . Yoon , N . Li et al., Multicomponent electrocatalyst with ultralow Pt loading and high hydrogen evolution activity. Nat. Energy 3, 773-782 ( 2018). https://doi.org/10.1038/s41560-018-0209-x
11.	H . Zhang , P . An , W . Zhou , B.Y . Guan , P . Zhang et al., Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction. Sci. Adv. 4, eaao6657 ( 2018). https://doi.org/10.1126/sciadv.aao6657
12.	H . Wei , K . Huang , D . Wang , R . Zhang , B . Ge et al., Iced photochemical reduction to synthesize atomically dispersed metals by suppressing nanocrystal growth. Nat. Commun. 8, 1490 ( 2017). https://doi.org/10.1038/s41467-017-01521-4
13.	X . Li , J . Yu , J . Jia , A . Wang , L . Zhao et al., Confined distribution of platinum clusters on MoO ₂hexagonal nanosheets with oxygen vacancies as a high-efficiency electrocatalyst for hydrogen evolution reaction. Nano Energy 62, 127-135 ( 2019). https://doi.org/10.1016/j.nanoen.2019.05.013
14.	N . Cheng , S . Stambula , D . Wang , M.N . Banis , J . Liu et al., Platinum single-atom and cluster catalysis of the hydrogen evolution reaction. Nat. Commun. 7, 13638 ( 2016). https://doi.org/10.1038/ncomms13638
15.	D . Liu , X . Li , S . Chen , H . Yan , C . Wang et al., Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution. Nat. Energy 4, 512-518 ( 2019). https://doi.org/10.1038/s41560-019-0402-6
16.	J . Dendooven , R.K . Ramachandran , E . Solano , M . Kurttepeli , L . Geerts et al., Independent tuning of size and coverage of supported Pt nanoparticles using atomic layer deposition. Nat. Commun. 8, 1074 ( 2017). https://doi.org/10.1038/s41467-017-01140-z
17.	I.J . Hsu , Y.C . Kimmel , X . Jiang , B.G . Willis , J.G . Chen , Atomic layer deposition synthesis of platinum-tungsten carbide core-shell catalysts for the hydrogen evolution reaction. Chem. Commun. 48, 1063-1065 ( 2012). https://doi.org/10.1039/C1CC15812K
18.	Y . Da , Z . Tian , R . Jiang , G . Chen , Y . Liu et al., Single-atom Pt doping induced p-type to n-type transition in NiO nanosheets toward self-gating modulated electrocatalytic hydrogen evolution reaction. ACS Nano 17, 18539-18547 ( 2023). https://doi.org/10.1021/acsnano.3c06595
19.	Z . Chen , X . Li , J . Zhao , S . Zhang , J . Wang et al., Stabilizing Pt single atoms through Pt-Se electron bridges on vacancy-enriched nickel selenide for efficient electrocatalytic hydrogen evolution. Angew. Chem. Int. Ed. 62, e202308686 ( 2023). https://doi.org/10.1002/anie.202308686
20.	Y . Da , Z . Tian , R . Jiang , Y . Liu , X . Lian et al., Dual Pt-Ni atoms dispersed on N-doped carbon nanostructure with novel (NiPt)-N ₄C ₂configurations for synergistic electrocatalytic hydrogen evolution reaction. Sci. China Mater. 66, 1389-1397 ( 2023). https://doi.org/10.1007/s40843-022-2249-9
21.	L . Chen , Y . Huang , Y . Ding , P . Yu , F . Huang et al., Interfacial engineering of atomic platinum-doped molybdenum carbide quantum dots for high-rate and stable hydrogen evolution reaction in proton exchange membrane water electrolysis. Nano Res. 16, 12186-12195 ( 2023). https://doi.org/10.1007/s12274-023-5666-2
22.	Z . Zeng , S . Küspert , S.E . Balaghi , H.E.M . Hussein , N . Ortlieb et al., Ultrahigh mass activity Pt entities consisting of Pt single atoms, clusters, and nanoparticles for improved hydrogen evolution reaction. Small 19, e2205885 ( 2023). https://doi.org/10.1002/smll.202205885
23.	Y . Qu , B . Chen , Z . Li , X . Duan , L . Wang et al., Thermal emitting strategy to synthesize atomically dispersed Pt metal sites from bulk Pt metal. J. Am. Chem. Soc. 141, 4505-4509 ( 2019). https://doi.org/10.1021/jacs.8b09834
24.	T . Wang , M . Park , Q . He , Z . Ding , Q . Yu et al., Low-cost scalable production of freestanding two-dimensional metallic nanosheets by polymer surface buckling enabled exfoliation. Cell. Rep. Phys. Sci. 1(11), 100235 ( 2020). https://doi.org/10.1016/j.xcrp.2020.100235
25.	T . Wang , Z . Zhang , M . Park , Q . Yu , Y . Yang , Etching-free ultrafast fabrication of self-rolled metallic nanosheets with controllable twisting. Nano Lett. 21, 7159-7165 ( 2021). https://doi.org/10.1021/acs.nanolett.1c01789
26.	T . Wang , Q . He , J . Zhang , Z . Ding , F . Li et al., The controlled large-area synthesis of two dimensional metals. Mater. Today 36, 30-39 ( 2020). https://doi.org/10.1016/j.mattod.2020.02.003
27.	H . Wu , C . Feng , L . Zhang , J . Zhang , D.P . Wilkinson , Non-noble metal electrocatalysts for the hydrogen evolution reaction in water electrolysis. Electrochem. Energy Rev. 4, 473-507 ( 2021). https://doi.org/10.1007/s41918-020-00086-z
28.	J.C . Meier , C . Galeano , I . Katsounaros , J . Witte , H.J . Bongard et al., Design criteria for stable Pt/C fuel cell catalysts. Beilstein J. Nanotechnol. 5, 44-67 ( 2014). https://doi.org/10.3762/bjnano.5.5
29.	Q . Yu , J . Zhang , J . Li , T . Wang , M . Park et al., Strong, ductile, and tough nanocrystal-assembled freestanding gold nanosheets. Nano Lett. 22, 822-829 ( 2022). https://doi.org/10.1021/acs.nanolett.1c04553
30.	M . Park , D . Li , T . Wang , B . Zhou , Y.Y . Li et al., Elasto-capillary manipulation of freestanding inorganic nanosheets: an implication for nano-manufacturing of low-dimensional structures. Adv. Mater. Interfaces 9, 2200355 2022). https://doi.org/10.1002/admi.202200355
31.	J . Zhang , Q . Yu , Q . Wang , J . Li , Z . Zhang et al., Strong yet ductile high entropy alloy derived nanostructured cermet. Nano Lett. 22, 7370-7377 ( 2022). https://doi.org/10.1021/acs.nanolett.2c02097
32.	B . Ravel , M . Newville , ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 12, 537-541 ( 2005). https://doi.org/10.1107/s0909049505012719
33.	S.I . Zabinsky , J.J . Rehr , A . Ankudinov , R.C . Albers , M.J . Eller , Multiple-scattering calculations of X-ray-absorption spectra. Phys. Rev. B 52, 2995-3009 ( 1995). https://doi.org/10.1103/physrevb.52.2995
34.	J . Kibsgaard , T.F . Jaramillo , F . Besenbacher , Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate[Mo ₃S ₁₃] ₂- clusters. Nat. Chem. 6, 248-253 ( 2014). https://doi.org/10.1038/nchem.1853
35.	Z . Jia , T . Yang , L . Sun , Y . Zhao , W . Li et al., A novel multinary intermetallic as an active electrocatalyst for hydrogen evolution. Adv. Mater. 32, e2000385 ( 2020). https://doi.org/10.1002/adma.202000385
36.	X . Zhang , Y . Yang , Y . Liu , Z . Jia , Q . Wang et al., Defect engineering of a high-entropy metallic glass surface for high-performance overall water splitting at ampere-level current densities. Adv. Mater. 35, e2303439 ( 2023). https://doi.org/10.1002/adma.202303439
37.	C . Lee , X . Wei , J.W . Kysar , J . Hone , Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321, 385-388 ( 2008). https://doi.org/10.1126/science.1157996
38.	C . Cao , S . Mukherjee , J . Liu , B . Wang , M . Amirmaleki et al., Role of graphene in enhancing the mechanical properties of TiO ₂/graphene heterostructures. Nanoscale 9, 11678-11684 ( 2017). https://doi.org/10.1039/C7NR03049E
39.	G . Kresse , J . Furthmüller , Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set. Comput. Mater. Sci. 6, 15-50 ( 1996). https://doi.org/10.1016/0927-0256(96)00008-0
40.	R . Michalsky , Y.-J . Zhang , A.A . Peterson , Trends in the hydrogen evolution activity of metal carbide catalysts. ACS Catal. 4, 1274-1278 ( 2014). https://doi.org/10.1021/cs500056u
41.	B . You , M.T . Tang , C . Tsai , F . Abild-Pedersen , X . Zheng et al., Enhancing electrocatalytic water splitting by strain engineering. Adv. Mater. 31, e1807001 ( 2019). https://doi.org/10.1002/adma.201807001
42.	J.K . Nørskov , T . Bligaard , A . Logadottir , J.R . Kitchin , J.G . Chen et al., Trends in the exchange current for hydrogen evolution. J. Electrochem. Soc. 152, J23 ( 2005). https://doi.org/10.1149/1.1856988
43.	H . Wang , Q . He , X . Gao , Y . Shang , W . Zhu et al., Multifunctional high entropy alloys enabled by severe lattice distortion. Adv. Mater. ( 2023). https://doi.org/10.1002/adma.202305453
44.	Y . Pu , Y . Niu , Y . Wang , S . Liu , B . Zhang , Statistical morphological identification of low-dimensional nanomaterials by using TEM. Particuology 61, 11-17 ( 2022). https://doi.org/10.1016/j.partic.2021.03.013
45.	J . Li , Y . Chen , Q . He , X . Xu , H . Wang et al., Heterogeneous lattice strain strengthening in severely distorted crystalline solids. Proc. Natl. Acad. Sci. 119, 1-7 ( 2022). https://doi.org/10.1073/pnas.2200607119
46.	G . Greczynski , L . Hultman , X-ray photoelectron spectroscopy: towards reliable binding energy referencing. Prog. Mater. Sci. 107, 100591 ( 2020). https://doi.org/10.1016/j.pmatsci.2019.100591
47.	C.G . Morales-Guio , L.A . Stern , X . Hu , Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution. Chem. Soc. Rev. 43, 6555-6569 ( 2014). https://doi.org/10.1039/c3cs60468c
48.	J . Kibsgaard , I . Chorkendorff , Considerations for the scaling-up of water splitting catalysts. Nat. Energy 4, 430-433 ( 2019). https://doi.org/10.1038/s41560-019-0407-1
49.	C . Wan , Z . Zhang , J . Dong , M . Xu , H . Pu et al., Amorphous nickel hydroxide shell tailors local chemical environment on platinum surface for alkaline hydrogen evolution reaction. Nat. Mater. 22, 1022-1029 ( 2023). https://doi.org/10.1038/s41563-023-01584-3
50.	M . Luo , S . Guo , Strain-controlled electrocatalysis on multimetallic nanomaterials. Nat. Rev. Mater. 2, 17059 ( 2017). https://doi.org/10.1038/natrevmats.2017.59
51.	T . He , W . Wang , F . Shi , X . Yang , X . Li et al., Mastering the surface strain of platinum catalysts for efficient electrocatalysis. Nature 598, 76-81 ( 2021). https://doi.org/10.1038/s41586-021-03870-z
52.	K . Yan , T.A . Maark , A . Khorshidi , V.A . Sethuraman , A.A . Peterson et al. The influence of elastic strain on catalytic activity in the hydrogen evolution reaction. Angew. Chem. Intern. Ed. 55, 6175-6181 ( 2016). https://doi.org/10.1002/anie.201508613
53.	H . Li , C . Tsai , A.L . Koh , L . Cai , A.W . Contryman et al., Activating and optimizing MoS ₂basal planes for hydrogen evolution through the formation of strained sulphur vacancies. Nat. Mater. 15, 364-364 ( 2016). https://doi.org/10.1038/nmat4564
54.	M . Erbi , H . Amara , R . Gatti , Tuning elastic properties of metallic nanoparticles by shape controlling: from atomistic to continuous models. ArXiv Preprint ArXiv: 2303.06995( 2023).
55.	Q.F . He , J.G . Wang , H.A . Chen , Z.Y . Ding , Z.Q . Zhou et al., A highly distorted ultraelastic chemically complex Elinvar alloy. Nature 602, 251-257 ( 2022). https://doi.org/10.1038/s41586-021-04309-1
56.	Y.F . Ye , C.T . Liu , Y . Yang , A geometric model for intrinsic residual strain and phase stability in high entropy alloys. Acta Mater. 94, 152-161 ( 2015). https://doi.org/10.1016/j.actamat.2015.04.051
57.	D . Deng , K.S . Novoselov , Q . Fu , N . Zheng , Z . Tian et al., Catalysis with two-dimensional materials and their heterostructures. Nat. Nanotechn. 11, 218-230 ( 2016). https://doi.org/10.1038/nnano.2015.340
58.	J.-J . Wang , X.-P . Li , B.-F . Cui , Z . Zhang , X.-F . Hu et al., A review of non-noble metal-based electrocatalysts for CO ₂electroreduction. Rare Met. 40, 3019-3037 ( 2021). https://doi.org/10.1007/s12598-021-01736-x
59.	H . Jin , C . Guo , X . Liu , J . Liu , A . Vasileff et al., Emerging two-dimensional nanomaterials for electrocatalysis. Chem. Rev. 118, 6337-6408 ( 2018). https://doi.org/10.1021/acs.chemrev.7b00689
60.	M . Luo , Y . Yang , Y . Sun , Y . Qin , C . Li et al., Ultrathin two-dimensional metallic nanocrystals for renewable energy electrocatalysis. Mater. Today 23, 45-56 ( 2019). https://doi.org/10.1016/j.mattod.2018.06.005
61.	S . Hu , S . Ge , H . Liu , X . Kang , Q . Yu et al., Low-dimensional electrocatalysts for acidic oxygen evolution: intrinsic activity, high current density operation, and long-term stability. Adv. Funct. Mater. 32, 2201726 ( 2022). https://doi.org/10.1002/adfm.202201726
62.	P . Chu , J . Finch , G . Bournival , S . Ata , C . Hamlett et al., A review of bubble break-up. Adv. Colloid Interface Sci. 270, 108-122 ( 2019). https://doi.org/10.1016/j.cis.2019.05.010

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