Significance of Activation Energy in Process Metallurgy
2013
A study of thermal behaviour, thermal degradation kinetics, and effect of composition on flow characterisation of
blast furnace
slagis important to Understanding the flow characteristics of
blast furnace(B/F)
slag. It is an important parameter for efficiency/productivity of a
blast furnace. In the present study flow characteristics of five different B/F
slag(C/S: 1.04, 1.192, 1.107, 1.101, and 1.189) were investigated. This study was predominantly based on the estimation of
activation energy. The
activation energywas estimated using two methods: differential scanning calorimetry (DSC) and High temperature
viscometer. DSC of different
slagwere measured at 30-1300oC @ 2o, 4o, 6o, 8o and 10oC/min.
Activation energywas estimated from such DSC plots using Kissinger and Ozawa methods. It was observed that
activation energyis largely dependent on C/S ratio of B/F
Slag– The
activation energydecreases with increase in C/S ratio. The flow characteristics of different B/F
slagwere also investigated by high temperature heating microscope, X-ray diffraction (XRD) and scanning electron microscope (SEM). The estimated IDT (initial deformation temperature), ST (softening temperature), HT (hemispherical temperature) and FT (fusion temperature) of different B/F
slagwas shown in table. Phase analysis of XRD and SEM micrographs support the results of flow characteristics measured by heating microscope.
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